Well, those are all entry level stuff that you have watched.
Maybe try some less known but very good stuff.
For series I would go:
Baccano! - well written, alright action, great characters
Haibane Renmei - fantastic characters and themes
Hyouka - eh, my personal choice, interesting characters and themes
Katanagatari - weird characters, fantastic dialogue and humor, nice action scenes
Kill la Kill - Over the top action
Kino no Tabi - watch it for the characters and story
Mahou Shojo Madoka Magica - interesting story and themes… very interesting story and themes
Crest of the Stars - google the order of watching, there are few series, i love this space opera
Tatami Galaxy - awesome characters, great themes
Terror in Resonance - good story
For movies I would go:
Akira - cult film, great soundtrack and animation, real piece of history
Ghost in the Shell - one more classic, can’t get more philosophical than this, also great action
Little Witch Academia - watch it for fun
Redline - fabulous animation, over the top adrenaline scenes, much fun, watch with bunch of friends and laugh your ass off
Sword of the Stranger - great animation, music and fight scenes
Pretty much anything from Miyazaki Hayao (and Ghibli studio in general), Satoshi Kon, Mamoru Hosoda, Yasuhiro Yoshiura. These guys know how to make a movie.